A
photon is an
elementary particle, the
quantum of
light and all other forms of
electromagnetic radiation, and the
force carrier for the
electromagnetic force, even when
static via
virtual photons. The effects of this
force are easily observable at both the
microscopic and
macroscopic level, because the photon has no
rest mass; this allows for
interactions at long distances. Like all elementary particles, photons are currently best explained by
quantum mechanics and exhibit
wave–particle duality, exhibiting properties of both
waves and
particles. For example, a single photon may be
refracted by a
lens or exhibit
wave interference with itself, but also act as a particle giving a definite result when its
position is measured.
The modern concept of the photon was developed gradually by
Albert Einstein to explain experimental observations that did not fit the classical
wave model
of light. In particular, the photon model accounted for the frequency
dependence of light's energy, and explained the ability of
matter and
radiation to be in
thermal equilibrium. It also accounted for anomalous observations, including the properties of
black body radiation, that other physicists, most notably
Max Planck, had sought to explain using
semiclassical models, in which light is still described by
Maxwell's equations, but the material objects that emit and absorb light, do so in amounts of energy that are
quantized
(i.e., they change energy only by certain particular discrete amounts
and cannot change energy in any arbitrary way). Although these
semiclassical models contributed to the development of quantum
mechanics, many further experiments
[2][3] starting with
Compton scattering of single photons by electrons, first observed in 1923, validated Einstein's hypothesis that
light itself is
quantized. In 1926 the chemist
Gilbert N. Lewis coined the name
photon for these particles, and after 1927, when
Arthur H. Compton won the Nobel Prize for his scattering studies, most scientists accepted the validity that
quanta of light have an independent existence, and Lewis' term
photon for light quanta was accepted.
In the
Standard Model of
particle physics, photons are described as a necessary consequence of physical laws having a certain
symmetry at every point in
spacetime. The intrinsic properties of photons, such as
charge,
mass and
spin, are determined by the properties of this
gauge symmetry. The photon concept has led to momentous advances in experimental and theoretical physics, such as
lasers,
Bose–Einstein condensation,
quantum field theory, and the
probabilistic interpretation of quantum mechanics. It has been applied to
photochemistry,
high-resolution microscopy, and
measurements of molecular distances. Recently, photons have been studied as elements of
quantum computers and for sophisticated applications in
optical communication such as
quantum cryptography.
Nomenclature
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In 1900, Max Planck was working on black-body radiation and suggested
that the energy in electromagnetic waves could only be released in
"packets" of energy. In his 1901 article
[4] in
Annalen der Physik he called these packets "energy elements". The word
quanta (singular
quantum) was used even before 1900 to mean particles or amounts of different
quantities, including
electricity. Later, in 1905
Albert Einstein went further by suggesting that electromagnetic waves could only exist in these discrete wave-packets.
[5] He called such a
wave-packet
the light quantum (German:
das Lichtquant). The name
photon derives from the
Greek word for light,
φῶς (transliterated
phôs), and was coined
[Note 1] in 1926 by the physical chemist
Gilbert Lewis, who published a speculative theory in which photons were "uncreatable and indestructible".
[6] Although Lewis' theory was never accepted as it was contradicted by many experiments, his new name,
photon, was adopted immediately by most physicists.
Isaac Asimov credits
Arthur Compton with defining quanta of energy as photons in 1923.
[7][8]
In physics, a photon is usually denoted by the symbol
γ (the
Greek letter gamma). This symbol for the photon probably derives from
gamma rays, which were discovered in 1900 by
Paul Villard,
[9][10] named by
Ernest Rutherford in 1903, and shown to be a form of
electromagnetic radiation in 1914 by Rutherford and
Edward Andrade.
[11] In
chemistry and
optical engineering, photons are usually symbolized by
hν, the energy of a photon, where
h is
Planck's constant and the
Greek letter ν (
nu) is the photon's
frequency. Much less commonly, the photon can be symbolized by
hf, where its frequency is denoted by
f.
Physical properties
The photon is
massless,
[Note 2] has no
electric charge,
[12] and is
stable. A photon has two possible
polarization states and is described by exactly three continuous parameters: the components of its
wave vector, which determine its wavelength
λ and its direction of propagation. The photon is the
gauge boson for
electromagnetism,
[13] and therefore all other quantum numbers of the photon (such as
lepton number,
baryon number, and
flavour quantum numbers) are zero.
[14]
Photons are emitted in many natural processes. For example, when a charge is
accelerated it emits
synchrotron radiation. During a
molecular,
atomic or
nuclear transition to a lower
energy level, photons of various energy will be emitted, from
infrared light to
gamma rays. A photon can also be emitted when a particle and its corresponding
antiparticle are
annihilated (for example,
electron-positron annihilation).
In empty space, the photon moves at
c (the
speed of light) and its
energy and
momentum are related by
E = pc, where
p is the
magnitude of the momentum
vector p. This derives from the following relativistic relation, with
m = 0:
[15]

The energy and momentum of a photon depend only on its
frequency (
ν) or inversely, its
wavelength (
λ):


where
k is the
wave vector (where the wave number
k = |k| = 2π/λ),
ω = 2πν is the
angular frequency, and
ħ = h/2π is the
reduced Planck constant.
[16]
Since
p points in the direction of the photon's propagation, the magnitude of the momentum is

The photon also carries
spin angular momentum that does not depend on its frequency.
[17] The magnitude of its spin is

and the component measured along its direction of motion, its
helicity, must be ±ħ. These two possible helicities, called right-handed and left-handed, correspond to the two possible
circular polarization states of the photon.
[18]
To illustrate the significance of these formulae, the annihilation of
a particle with its antiparticle in free space must result in the
creation of at least
two photons for the following reason. In the
center of mass frame,
the colliding antiparticles have no net momentum, whereas a single
photon always has momentum (since it is determined, as we have seen,
only by the photon's frequency or wavelength—which cannot be zero).
Hence,
conservation of momentum (or equivalently,
translational invariance)
requires that at least two photons are created, with zero net momentum.
(However, it is possible if the system interacts with another particle
or field for annihilation to produce one photon, as when a positron
annihilates with a bound atomic electron, it is possible for only one
photon to be emitted, as the nuclear Coulomb field breaks translational
symmetry.) The energy of the two photons, or, equivalently, their
frequency, may be determined from
conservation of four-momentum. Seen another way, the photon can be considered as its own antiparticle. The reverse process,
pair production, is the dominant mechanism by which high-energy photons such as
gamma rays lose energy while passing through matter.
[19] That process is the reverse of "annihilation to one photon" allowed in the electric field of an atomic nucleus.
The classical formulae for the energy and momentum of
electromagnetic radiation can be re-expressed in terms of photon events. For example, the
pressure of electromagnetic radiation
on an object derives from the transfer of photon momentum per unit time
and unit area to that object, since pressure is force per unit area and
force is the change in
momentum per unit time.
[20]
Experimental checks on photon mass
The photon is currently understood to be strictly massless, but this
is an experimental question. If the photon is not a strictly massless
particle, it would not move at the exact speed of light in vacuum,
c. Its speed would be lower and depend on its frequency. Relativity would be unaffected by this; the so-called speed of light,
c,
would then not be the actual speed at which light moves, but a constant
of nature which is the maximum speed that any object could
theoretically attain in space-time.
[21] Thus, it would still be the speed of space-time ripples (
gravitational waves and
gravitons), but it would not be the speed of photons.
A massive photon would have other effects as well.
Coulomb's law
would be modified and the electromagnetic field would have an extra
physical degree of freedom. These effects yield more sensitive
experimental probes of the photon mass than the frequency dependence of
the speed of light. If Coulomb's law is not exactly valid, then that
would cause the presence of an
electric field inside a hollow conductor when it is subjected to an external electric field. This thus allows one to
test Coulomb's law to very high precision.
[22] A null result of such an experiment has set a limit of
m ≲ 10
−14 eV/c
2.
[23]
Sharper upper limits have been obtained in experiments designed to detect effects caused by the galactic
vector potential. Although the galactic vector potential is very large because the galactic
magnetic field
exists on very long length scales, only the magnetic field is
observable if the photon is massless. In case of a massive photon, the
mass term

would affect the galactic plasma. The fact that no such effects are seen implies an upper bound on the photon mass of
m <
3×10−27 eV/c2.
[24] The galactic vector potential can also be probed directly by measuring the torque exerted on a magnetized ring.
[25] Such methods were used to obtain the sharper upper limit of 10
−18eV/c
2 (the equivalent of
1.07×10−27 atomic mass units) given by the Particle Data Group.
[26]
These sharp limits from the non-observation of the effects caused by
the galactic vector potential have been shown to be model dependent.
[27] If the photon mass is generated via the
Higgs mechanism then the upper limit of
m≲10
−14 eV/c
2 from the test of Coulomb's law is valid.
Photons inside
superconductors do develop a nonzero
effective rest mass; as a result, electromagnetic forces become short-range inside superconductors.
Historical development
In most theories up to the eighteenth century, light was pictured as being made up of particles. Since
particle models cannot easily account for the
refraction,
diffraction and
birefringence of light, wave theories of light were proposed by
René Descartes (1637),
[28] Robert Hooke (1665),
[29] and
Christian Huygens (1678);
[30] however, particle models remained dominant, chiefly due to the influence of
Isaac Newton.
[31] In the early nineteenth century,
Thomas Young and
August Fresnel clearly demonstrated the
interference and diffraction of light and by 1850 wave models were generally accepted.
[32] In 1865,
James Clerk Maxwell's
prediction[33] that light was an electromagnetic wave—which was confirmed experimentally in 1888 by
Heinrich Hertz's detection of
radio waves[34]—seemed to be the final blow to particle models of light.
In 1900,
Maxwell's theoretical model of light as oscillating
electric and
magnetic fields seemed complete. However, several observations could not be explained by any wave model of
electromagnetic radiation, leading to the idea that light-energy was packaged into
quanta described by E=hν. Later experiments showed that these light-quanta also carry momentum and, thus, can be considered
particles: the
photon concept was born, leading to a deeper understanding of the electric and magnetic fields themselves.
The
Maxwell wave theory, however, does not account for
all properties of light. The Maxwell theory predicts that the energy of a light wave depends only on its
intensity, not on its
frequency;
nevertheless, several independent types of experiments show that the
energy imparted by light to atoms depends only on the light's frequency,
not on its intensity. For example,
some chemical reactions
are provoked only by light of frequency higher than a certain
threshold; light of frequency lower than the threshold, no matter how
intense, does not initiate the reaction. Similarly, electrons can be
ejected from a metal plate by shining light of sufficiently high
frequency on it (the
photoelectric effect); the energy of the ejected electron is related only to the light's frequency, not to its intensity.
[35][Note 3]
At the same time, investigations of
blackbody radiation carried out over four decades (1860–1900) by various researchers
[36] culminated in
Max Planck's
hypothesis[4][37] that the energy of
any system that absorbs or emits electromagnetic radiation of frequency
ν is an integer multiple of an energy quantum
E=hν. As shown by
Albert Einstein,
[5][38] some form of energy quantization
must be assumed to account for the thermal equilibrium observed between matter and
electromagnetic radiation; for this explanation of the
photoelectric effect, Einstein received the 1921
Nobel Prize in physics.
[39]
Since the Maxwell theory of light allows for all possible energies of
electromagnetic radiation, most physicists assumed initially that the
energy quantization resulted from some unknown constraint on the matter
that absorbs or emits the radiation. In 1905, Einstein was the first to
propose that energy quantization was a property of electromagnetic
radiation itself.
[5]
Although he accepted the validity of Maxwell's theory, Einstein pointed
out that many anomalous experiments could be explained if the
energy
of a Maxwellian light wave were localized into point-like quanta that
move independently of one another, even if the wave itself is spread
continuously over space.
[5] In 1909
[38] and 1916,
[40] Einstein showed that, if
Planck's law of black-body radiation is accepted, the energy quanta must also carry
momentum p=h/λ, making them full-fledged
particles. This photon momentum was observed experimentally
[41] by
Arthur Compton, for which he received the
Nobel Prize
in 1927. The pivotal question was then: how to unify Maxwell's wave
theory of light with its experimentally observed particle nature? The
answer to this question occupied
Albert Einstein for the rest of his life,
[42] and was solved in
quantum electrodynamics and its successor, the
Standard Model (see
Second quantization and
The photon as a gauge boson, below).
Early objections
Up to 1923, most physicists were reluctant to accept that light itself
was quantized. Instead, they tried to explain photon behavior by
quantizing only
matter, as in the
Bohr model of the
hydrogen atom
(shown here). Even though these semiclassical models were only a first
approximation, they were accurate for simple systems and they led to
quantum mechanics.
Einstein's 1905 predictions were verified experimentally in several
ways in the first two decades of the 20th century, as recounted in
Robert Millikan's Nobel lecture.
[43] However, before
Compton's experiment[41] showing that photons carried
momentum proportional to their
wave number (or frequency) (1922), most physicists were reluctant to believe that
electromagnetic radiation itself might be particulate. (See, for example, the Nobel lectures of
Wien,
[36] Planck[37] and Millikan.
[43]).
Instead, there was a widespread belief that energy quantization
resulted from some unknown constraint on the matter that absorbs or
emits radiation. Attitudes changed over time. In part, the change can be
traced to experiments such as
Compton scattering, where it was much more difficult not to ascribe quantization to light itself to explain the observed results.
[44]
Even after Compton's experiment,
Niels Bohr,
Hendrik Kramers and
John Slater made one last attempt to preserve the Maxwellian continuous electromagnetic field model of light, the so-called
BKS model.
[45] To account for the data then available, two drastic hypotheses had to be made:
- Energy and momentum are conserved only on the average in
interactions between matter and radiation, not in elementary processes
such as absorption and emission. This allows one to reconcile the
discontinuously changing energy of the atom (jump between energy states)
with the continuous release of energy into radiation.
- Causality is abandoned. For example, spontaneous emissions are merely emissions induced by a "virtual" electromagnetic field.
However, refined Compton experiments showed that energy-momentum is
conserved extraordinarily well in elementary processes; and also that
the jolting of the electron and the generation of a new photon in
Compton scattering obey causality to within 10
ps. Accordingly, Bohr and his co-workers gave their model "as honorable a funeral as possible".
[42] Nevertheless, the failures of the BKS model inspired
Werner Heisenberg in his development of
matrix mechanics.
[46]
A few physicists persisted
[47] in developing semiclassical models in which
electromagnetic radiation is not quantized, but matter appears to obey the laws of
quantum mechanics.
Although the evidence for photons from chemical and physical
experiments was overwhelming by the 1970s, this evidence could not be
considered as
absolutely definitive; since it relied on the
interaction of light with matter, a sufficiently complicated theory of
matter could in principle account for the evidence. Nevertheless,
all semiclassical theories were refuted definitively in the 1970s and 1980s by photon-correlation experiments.
[Note 4] Hence, Einstein's hypothesis that quantization is a property of light itself is considered to be proven.
Wave–particle duality and uncertainty principles
Photons, like all quantum objects, exhibit both wave-like and
particle-like properties. Their dual wave–particle nature can be
difficult to visualize. The photon displays clearly wave-like phenomena
such as
diffraction and
interference on the length scale of its wavelength. For example, a single photon passing through a
double-slit experiment
lands on the screen exhibiting interference phenomena but only if no
measure was made on the actual slit being run across. To account for the
particle interpretation that phenomenon is called
probability distribution but behaves according to
Maxwell's equations.
[48] However, experiments confirm that the photon is
not a short pulse of electromagnetic radiation; it does not spread out as it propagates, nor does it divide when it encounters a
beam splitter.
[49] Rather, the photon seems to be a
point-like particle since it is absorbed or emitted
as a whole by arbitrarily small systems, systems much smaller than its wavelength, such as an atomic nucleus (≈10
−15 m across) or even the point-like
electron. Nevertheless, the photon is
not a point-like particle whose trajectory is shaped probabilistically by the
electromagnetic field, as conceived by
Einstein
and others; that hypothesis was also refuted by the photon-correlation
experiments cited above. According to our present understanding, the
electromagnetic field itself is produced by photons, which in turn
result from a local
gauge symmetry and the laws of
quantum field theory (see the
Second quantization and
Gauge boson sections below).
A key element of
quantum mechanics is
Heisenberg's uncertainty principle,
which forbids the simultaneous measurement of the position and momentum
of a particle along the same direction. Remarkably, the uncertainty
principle for charged, material particles
requires the
quantization of light into photons, and even the frequency dependence of
the photon's energy and momentum. An elegant illustration is
Heisenberg's
thought experiment for locating an electron with an ideal microscope.
[50] The position of the electron can be determined to within the
resolving power of the microscope, which is given by a formula from classical
optics

where

is the
aperture angle of the microscope. Thus, the position uncertainty

can be made arbitrarily small by reducing the wavelength λ. The
momentum of the electron is uncertain, since it received a "kick"

from the light scattering from it into the microscope. If light were
not quantized into photons, the uncertainty

could be made arbitrarily small by reducing the light's intensity. In
that case, since the wavelength and intensity of light can be varied
independently, one could simultaneously determine the position and
momentum to arbitrarily high accuracy, violating the
uncertainty principle.
By contrast, Einstein's formula for photon momentum preserves the
uncertainty principle; since the photon is scattered anywhere within the
aperture, the uncertainty of momentum transferred equals

giving the product

,
which is Heisenberg's uncertainty principle. Thus, the entire world is
quantized; both matter and fields must obey a consistent set of quantum
laws, if either one is to be quantized.
[51]
The analogous uncertainty principle for photons forbids the simultaneous measurement of the number

of photons (see
Fock state and the
Second quantization section below) in an electromagnetic wave and the phase

of that wave

See
coherent state and
squeezed coherent state for more details.
Both photons and material particles such as electrons create analogous
interference patterns when passing through a
double-slit experiment. For photons, this corresponds to the interference of a
Maxwell light wave whereas, for material particles, this corresponds to the interference of the
Schrödinger wave equation. Although this similarity might suggest that
Maxwell's equations are simply Schrödinger's equation for photons, most physicists do not agree.
[52][53] For one thing, they are mathematically different; most obviously, Schrödinger's one equation solves for a
complex field, whereas Maxwell's four equations solve for
real fields. More generally, the normal concept of a Schrödinger
probability wave function cannot be applied to photons.
[54] Being massless, they cannot be localized without being destroyed; technically, photons cannot have a position eigenstate

, and, thus, the normal Heisenberg uncertainty principle

does not pertain to photons. A few substitute wave functions have been suggested for the photon,
[55][56][57][58]
but they have not come into general use. Instead, physicists generally
accept the second-quantized theory of photons described below,
quantum electrodynamics, in which photons are quantized excitations of electromagnetic modes.
Bose–Einstein model of a photon gas
In 1924,
Satyendra Nath Bose derived
Planck's law of black-body radiation without using any electromagnetism, but rather a modification of coarse-grained counting of
phase space.
[59]
Einstein showed that this modification is equivalent to assuming that
photons are rigorously identical and that it implied a "mysterious
non-local interaction",
[60][61] now understood as the requirement for a
symmetric quantum mechanical state. This work led to the concept of
coherent states and the development of the laser. In the same papers, Einstein extended Bose's formalism to material particles (
bosons) and predicted that they would condense into their lowest quantum state at low enough temperatures; this
Bose–Einstein condensation was observed experimentally in 1995.
[62]
The modern view on this is that photons are, by virtue of their integer spin,
bosons (as opposed to
fermions with half-integer spin). By the
spin-statistics theorem, all bosons obey Bose–Einstein statistics (whereas all fermions obey
Fermi-Dirac statistics).
[63]
Stimulated and spontaneous emission
Stimulated emission (in which photons "clone" themselves) was predicted by Einstein in his kinetic analysis, and led to the development of the
laser.
Einstein's derivation inspired further developments in the quantum
treatment of light, which led to the statistical interpretation of
quantum mechanics.
In 1916, Einstein showed that Planck's radiation law could be derived
from a semi-classical, statistical treatment of photons and atoms,
which implies a relation between the rates at which atoms emit and
absorb photons. The condition follows from the assumption that light is
emitted and absorbed by atoms independently, and that the thermal
equilibrium is preserved by interaction with atoms. Consider a cavity in
thermal equilibrium and filled with
electromagnetic radiation and atoms that can emit and absorb that radiation. Thermal equilibrium requires that the energy density

of photons with frequency

(which is proportional to their
number density) is, on average, constant in time; hence, the rate at which photons of any particular frequency are
emitted must equal the rate of
absorbing them.
[64]
Einstein began by postulating simple proportionality relations for
the different reaction rates involved. In his model, the rate

for a system to
absorb a photon of frequency

and transition from a lower energy

to a higher energy

is proportional to the number

of atoms with energy

and to the energy density

of ambient photons with that frequency,

where

is the
rate constant
for absorption. For the reverse process, there are two possibilities:
spontaneous emission of a photon, and a return to the lower-energy state
that is initiated by the interaction with a passing photon. Following
Einstein's approach, the corresponding rate

for the emission of photons of frequency

and transition from a higher energy

to a lower energy

is

where

is the rate constant for
emitting a photon spontaneously, and

is the rate constant for emitting it in response to ambient photons (
induced or stimulated emission).
In thermodynamic equilibrium, the number of atoms in state i and that
of atoms in state j must, on average, be constant; hence, the rates

and

must be equal. Also, by arguments analogous to the derivation of
Boltzmann statistics, the ratio of

and

is

where

are the
degeneracy of the state i and that of j, respectively,

their energies, k the
Boltzmann constant and T the system's
temperature. From this, it is readily derived that

and

The A and Bs are collectively known as the
Einstein coefficients.
[65]
Einstein could not fully justify his rate equations, but claimed that it should be possible to calculate the coefficients

,

and

once physicists had obtained "mechanics and electrodynamics modified to accommodate the quantum hypothesis".
[66] In fact, in 1926,
Paul Dirac derived the

rate constants in using a semiclassical approach,
[67] and, in 1927, succeeded in deriving
all the rate constants from first principles within the framework of quantum theory.
[68][69]
Dirac's work was the foundation of quantum electrodynamics, i.e., the
quantization of the electromagnetic field itself. Dirac's approach is
also called
second quantization or
quantum field theory;
[70][71][72] earlier quantum mechanical treatments only treat material particles as quantum mechanical, not the electromagnetic field.
Einstein was troubled by the fact that his theory seemed incomplete, since it did not determine the
direction of a spontaneously emitted photon. A probabilistic nature of light-particle motion was first considered by
Newton in his treatment of
birefringence
and, more generally, of the splitting of light beams at interfaces into
a transmitted beam and a reflected beam. Newton hypothesized that
hidden variables in the light particle determined which path it would
follow.
[31] Similarly, Einstein hoped for a more complete theory that would leave nothing to chance, beginning his separation
[42] from quantum mechanics. Ironically,
Max Born's
probabilistic interpretation of the
wave function[73][74] was inspired by Einstein's later work searching for a more complete theory.
[75]
Second quantization
Different
electromagnetic modes (such as those depicted here) can be treated as independent
simple harmonic oscillators. A photon corresponds to a unit of energy E=hν in its electromagnetic mode.
In 1910,
Peter Debye derived
Planck's law of black-body radiation from a relatively simple assumption.
[76] He correctly decomposed the electromagnetic field in a cavity into its
Fourier modes, and assumed that the energy in any mode was an integer multiple of

, where

is the frequency of the electromagnetic mode. Planck's law of
black-body radiation follows immediately as a geometric sum. However,
Debye's approach failed to give the correct formula for the energy
fluctuations of blackbody radiation, which were derived by Einstein in
1909.
[38]
In 1925,
Born,
Heisenberg and
Jordan reinterpreted Debye's concept in a key way.
[77] As may be shown classically, the
Fourier modes of the
electromagnetic field—a complete set of electromagnetic plane waves indexed by their wave vector
k and polarization state—are equivalent to a set of uncoupled
simple harmonic oscillators. Treated quantum mechanically, the energy levels of such oscillators are known to be

, where

is the oscillator frequency. The key new step was to identify an electromagnetic mode with energy

as a state with

photons, each of energy

. This approach gives the correct energy fluctuation formula.
Dirac took this one step further.
[68][69]
He treated the interaction between a charge and an electromagnetic
field as a small perturbation that induces transitions in the photon
states, changing the numbers of photons in the modes, while conserving
energy and momentum overall. Dirac was able to derive Einstein's

and

coefficients from first principles, and showed that the Bose–Einstein
statistics of photons is a natural consequence of quantizing the
electromagnetic field correctly (Bose's reasoning went in the opposite
direction; he derived
Planck's law of black body radiation by
assuming BE statistics). In Dirac's time, it was not yet known that all bosons, including photons, must obey BE statistics.
Dirac's second-order
perturbation theory can involve
virtual photons, transient intermediate states of the electromagnetic field; the static
electric and
magnetic interactions are mediated by such virtual photons. In such
quantum field theories, the
probability amplitude of observable events is calculated by summing over
all possible intermediate steps, even ones that are unphysical; hence, virtual photons are not constrained to satisfy

, and may have extra
polarization states; depending on the
gauge
used, virtual photons may have three or four polarization states,
instead of the two states of real photons. Although these transient
virtual photons can never be observed, they contribute measurably to the
probabilities of observable events. Indeed, such second-order and
higher-order perturbation calculations can give apparently
infinite contributions to the sum. Such unphysical results are corrected for using the technique of
renormalization.
Other virtual particles may contribute to the summation as well; for
example, two photons may interact indirectly through virtual
electron-
positron pairs.
[78]
In fact, such photon-photon scattering, as well as electron-photon
scattering, is meant to be one of the modes of operations of the planned
particle accelerator, the
International Linear Collider.
[79]
In modern physics notation, the
quantum state of the electromagnetic field is written as a
Fock state, a
tensor product of the states for each electromagnetic mode

where

represents the state in which

photons are in the mode

. In this notation, the creation of a new photon in mode

(e.g., emitted from an atomic transition) is written as

. This notation merely expresses the concept of Born, Heisenberg and Jordan described above, and does not add any physics.
The photon as a gauge boson
Main article:
Gauge theory
The electromagnetic field can be understood as a
gauge field, i.e., as a field that results from requiring that a gauge symmetry holds independently at every position in
spacetime.
[80] For the
electromagnetic field, this gauge symmetry is the
Abelian U(1) symmetry of a
complex number, which reflects the ability to vary the
phase of a complex number without affecting
observables or
real valued functions made from it, such as the
energy or the
Lagrangian.
The quanta of an
Abelian gauge field
must be massless, uncharged bosons, as long as the symmetry is not
broken; hence, the photon is predicted to be massless, and to have zero
electric charge and integer spin. The particular form of the
electromagnetic interaction specifies that the photon must have
spin ±1; thus, its
helicity must be

. These two spin components correspond to the classical concepts of
right-handed and left-handed circularly polarized light. However, the transient
virtual photons of
quantum electrodynamics may also adopt unphysical polarization states.
[80]
In the prevailing
Standard Model of physics, the photon is one of four
gauge bosons in the
electroweak interaction; the
other three are denoted W
+, W
− and Z
0 and are responsible for the
weak interaction. Unlike the photon, these gauge bosons have
mass, owing to a
mechanism that breaks their
SU(2) gauge symmetry. The unification of the photon with W and Z gauge bosons in the electroweak interaction was accomplished by
Sheldon Glashow,
Abdus Salam and
Steven Weinberg, for which they were awarded the 1979
Nobel Prize in physics.
[81][82][83] Physicists continue to hypothesize
grand unified theories that connect these four
gauge bosons with the eight
gluon gauge bosons of
quantum chromodynamics; however, key predictions of these theories, such as
proton decay, have not been observed experimentally.
[84]
Contributions to the mass of a system
The energy of a system that emits a photon is
decreased by the energy

of the photon as measured in the rest frame of the emitting system, which may result in a reduction in mass in the amount

. Similarly, the mass of a system that absorbs a photon is
increased
by a corresponding amount. As an application, the energy balance of
nuclear reactions involving photons is commonly written in terms of the
masses of the nuclei involved, and terms of the form

for the gamma photons (and for other relevant energies, such as the recoil energy of nuclei).
[85]
This concept is applied in key predictions of
quantum electrodynamics
(QED, see above). In that theory, the mass of electrons (or, more
generally, leptons) is modified by including the mass contributions of
virtual photons, in a technique known as
renormalization. Such "radiative corrections" contribute to a number of predictions of QED, such as the
magnetic dipole moment of
leptons, the
Lamb shift, and the
hyperfine structure of bound lepton pairs, such as
muonium and
positronium.
[86]
Since photons contribute to the
stress-energy tensor, they exert a
gravitational attraction on other objects, according to the theory of
general relativity. Conversely, photons are themselves affected by gravity; their normally straight trajectories may be bent by warped
spacetime, as in
gravitational lensing, and
their frequencies may be lowered by moving to a higher
gravitational potential, as in the
Pound-Rebka experiment. However, these effects are not specific to photons; exactly the same effects would be predicted for classical
electromagnetic waves.
[87]
Photons in matter
Light that travels through transparent matter does so at a lower speed than
c, the speed of light in a vacuum. In addition, light can also undergo
scattering and
absorption.
There are circumstances in which heat transfer through a material is
mostly radiative, involving emission and absorption of photons within
it. An example would be in the
core of the Sun. Energy can take about a million years to reach the surface.
[88]
However, this phenomenon is distinct from scattered radiation passing
diffusely through matter, as it involves local equilibration between the
radiation and the temperature. Thus, the time is how long it takes the
energy to be transferred, not the
photons
themselves. Once in open space, a photon from the Sun takes only 8.3
minutes to reach Earth. The factor by which the speed of light is
decreased in a material is called the
refractive index of the material. In a classical wave picture, the slowing can be explained by the light inducing
electric polarization
in the matter, the polarized matter radiating new light, and the new
light interfering with the original light wave to form a delayed wave.
In a particle picture, the slowing can instead be described as a
blending of the photon with quantum excitations of the matter (
quasi-particles such as
phonons and
excitons) to form a
polariton; this polariton has a nonzero
effective mass, which means that it cannot travel at
c.
Alternatively, photons may be viewed as
always traveling at
c,
even in matter, but they have their phase shifted (delayed or advanced)
upon interaction with atomic scatters: this modifies their wavelength
and momentum, but not speed.
[89]
A light wave made up of these photons does travel slower than the speed
of light. In this view the photons are "bare", and are scattered and
phase shifted, while in the view of the preceding paragraph the photons
are "dressed" by their interaction with matter, and move without
scattering or phase shifting, but at a lower speed.
Light of different frequencies may travel through matter at
different speeds; this is called
dispersion. In some cases, it can result in
extremely slow speeds of light in matter. The effects of photon interactions with other quasi-particles may be observed directly in
Raman scattering and
Brillouin scattering.
[90]
Photons can also be
absorbed by nuclei, atoms or molecules, provoking transitions between their
energy levels. A classic example is the molecular transition of
retinal C
20H
28O, which is responsible for
vision, as discovered in 1958 by Nobel laureate
biochemist George Wald and co-workers. The absorption provokes a
cis-trans isomerization
that, in combination with other such transitions, is transduced into
nerve impulses. The absorption of photons can even break chemical bonds,
as in the
photodissociation of
chlorine; this is the subject of
photochemistry.
[91][92] Analogously,
gamma rays can in some circumstances dissociate atomic nuclei in a process called
photodisintegration.
Technological applications
Photons have many applications in technology. These examples are chosen to illustrate applications of photons
per se,
rather than general optical devices such as lenses, etc. that could
operate under a classical theory of light. The laser is an extremely
important application and is discussed above under
stimulated emission.
Individual photons can be detected by several methods. The classic
photomultiplier tube exploits the
photoelectric effect: a photon landing on a metal plate ejects an electron, initiating an ever-amplifying avalanche of electrons.
Charge-coupled device chips use a similar effect in
semiconductors: an incident photon generates a charge on a microscopic
capacitor that can be detected. Other detectors such as
Geiger counters use the ability of photons to
ionize gas molecules, causing a detectable change in
conductivity.
[93]
Planck's energy formula

is often used by engineers and chemists in design, both to compute the
change in energy resulting from a photon absorption and to predict the
frequency of the light emitted for a given energy transition. For
example, the
emission spectrum of a
fluorescent light bulb
can be designed using gas molecules with different electronic energy
levels and adjusting the typical energy with which an electron hits the
gas molecules within the bulb.
[Note 5]
Under some conditions, an energy transition can be excited by "two"
photons that individually would be insufficient. This allows for higher
resolution microscopy, because the sample absorbs energy only in the
region where two beams of different colors overlap significantly, which
can be made much smaller than the excitation volume of a single beam
(see
two-photon excitation microscopy). Moreover, these photons cause less damage to the sample, since they are of lower energy.
[94]
In some cases, two energy transitions can be coupled so that, as one
system absorbs a photon, another nearby system "steals" its energy and
re-emits a photon of a different frequency. This is the basis of
fluorescence resonance energy transfer, a technique that is used in
molecular biology to study the interaction of suitable
proteins.
[95]
Several different kinds of
hardware random number generator
involve the detection of single photons. In one example, for each bit
in the random sequence that is to be produced, a photon is sent to a
beam-splitter.
In such a situation, there are two possible outcomes of equal
probability. The actual outcome is used to determine whether the next
bit in the sequence is "0" or "1".
[96][97]
Recent research
Much research has been devoted to applications of photons in the field of
quantum optics. Photons seem well-suited to be elements of an extremely fast
quantum computer, and the
quantum entanglement of photons is a focus of research.
Nonlinear optical processes are another active research area, with topics such as
two-photon absorption,
self-phase modulation,
modulational instability and
optical parametric oscillators. However, such processes generally do not require the assumption of photons
per se; they may often be modeled by treating atoms as nonlinear oscillators. The nonlinear process of
spontaneous parametric down conversion is often used to produce single-photon states. Finally, photons are essential in some aspects of
optical communication, especially for
quantum cryptography.
[Note 6]
See also
Notes
- ^ Although the 1967 Elsevier translation of Planck's Nobel Lecture interprets Planck's Lichtquant as "photon", the more literal 1922 translation by Hans Thacher Clarke and Ludwik Silberstein The origin and development of the quantum theory, The Clarendon Press, 1922 (here [1]) uses "light-quantum". No evidence is known that Planck himself used the term "photon" by 1926 (see also this note).
- ^ The mass
of the photon is believed to be exactly zero, based on experiment and
theoretical considerations described in the article. Some sources also
refer to the relativistic mass concept, which is just the energy scaled to units of mass. For a photon with wavelength λ or energy E, this is h/λc or E/c2. This usage for the term "mass" is no longer common in scientific literature. Further info: What is the mass of a photon? http://math.ucr.edu/home/baez/physics/ParticleAndNuclear/photon_mass.html
- ^ The phrase "no matter how intense" refers to intensities below approximately 1013 W/cm2 at which point perturbation theory begins to break down. In contrast, in the intense regime, which for visible light is above approximately 1014 W/cm2, the classical wave description correctly predicts the energy acquired by electrons, called ponderomotive energy. (See also: Boreham et al. (1996). "Photon density and the correspondence principle of electromagnetic interaction".) By comparison, sunlight is only about 0.1 W/cm2.
- ^ These
experiments produce results that cannot be explained by any classical
theory of light, since they involve anticorrelations that result from
the quantum measurement process. In 1974, the first such experiment was carried out by Clauser, who reported a violation of a classical Cauchy–Schwarz inequality. In 1977, Kimble et al.
demonstrated an analogous anti-bunching effect of photons interacting
with a beam splitter; this approach was simplified and sources of error
eliminated in the photon-anticorrelation experiment of Grangier et al. (1986). This work is reviewed and simplified further in Thorn et al. (2004). (These references are listed below under Additional references.)
- ^ An example is US Patent Nr. 5212709.
- ^ Introductory-level material on the various sub-fields of quantum optics can be found in Fox, M. (2006). Quantum Optics: An Introduction. Oxford University Press. ISBN 0-19-856673-5.
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Die Konstanten

and

würden sich direkt berechnen lassen, wenn wir im Besitz einer im Sinne
der Quantenhypothese modifizierten Elektrodynamik und Mechanik wären."
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- ^ Born, M. (1926). "Quantenmechanik der Stossvorgänge". Zeitschrift für Physik 38 (11–12): 803. Bibcode 1926ZPhy...38..803B. DOI:10.1007/BF01397184. (German)
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Specifically, Born claimed to have been inspired by Einstein's
never-published attempts to develop a "ghost-field" theory, in which
point-like photons are guided probabilistically by ghost fields that
follow Maxwell's equations.
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- ^ Born, M.; Heisenberg, W.; Jordan, P. (1925). "Quantenmechanik II". Zeitschrift für Physik 35 (8–9): 557–615. Bibcode 1926ZPhy...35..557B. DOI:10.1007/BF01379806. (German)
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- ^ Steven Weinberg Nobel lecture, delivered 8 December 1979.
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- ^ Radiative
correction to electron mass section 7-1-2, anomalous magnetic moments
section 7-2-1, Lamb shift section 7-3-2 and hyperfine splitting in
positronium section 10-3 in Itzykson, C.; Zuber, J.-B. (1980). Quantum Field Theory. McGraw-Hill. ISBN 0-07-032071-3.
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- ^ Ch 4 in Hecht, Eugene (2001). Optics. Addison Wesley. ISBN 978-0-8053-8566-3.
- ^ Polaritons section 10.10.1, Raman and Brillouin scattering section 10.11.3 in Patterson, J.D.; Bailey, B.C. (2007). Solid-State Physics: Introduction to the Theory. Springer. pp. 569 ff, 580 ff. ISBN 3-540-24115-9.
- ^ E.g., section 11-5 C in Pine, S.H.; Hendrickson, J.B.; Cram, D.J.; Hammond, G.S. (1980). Organic Chemistry (4th ed.). McGraw-Hill. ISBN 0-07-050115-7.
- ^ Nobel lecture given by G. Wald on December 12, 1967, online at nobelprize.org: The Molecular Basis of Visual Excitation.
- ^ Photomultiplier section 1.1.10, CCDs section 1.1.8, Geiger counters section 1.3.2.1 in Kitchin, C.R. (2008). Astrophysical Techniques. Boca Raton (FL): CRC Press. ISBN 1-4200-8243-4.
- ^ Denk, W.; Svoboda, K. (1997). "Photon upmanship: Why multiphoton imaging is more than a gimmick". Neuron 18 (3): 351–357. DOI:10.1016/S0896-6273(00)81237-4. PMID 9115730.
- ^ Lakowicz, J.R. (2006). Principles of Fluorescence Spectroscopy. Springer. pp. 529 ff. ISBN 0-387-31278-1.
- ^ Jennewein,
T.; Achleitner, U.; Weihs, G.; Weinfurter, H.; Zeilinger, A. (2000). "A
fast and compact quantum random number generator". Review of Scientific Instruments 71 (4): 1675–1680. arXiv:quant-ph/9912118. Bibcode 2000RScI...71.1675J. DOI:10.1063/1.1150518.
- ^ Stefanov, A.; Gisin, N.; Guinnard, O.; Guinnard, L.; Zbiden, H. (2000). "Optical quantum random number generator". Journal of Modern Optics 47 (4): 595–598. DOI:10.1080/095003400147908.
Additional references
By date of publication:
- Clauser, J.F. (1974). "Experimental
distinction between the quantum and classical field-theoretic
predictions for the photoelectric effect". Physical Review D 9 (4): 853–860. Bibcode 1974PhRvD...9..853C. DOI:10.1103/PhysRevD.9.853.
- Kimble, H.J.; Dagenais, M.; Mandel, L. (1977). "Photon Anti-bunching in Resonance Fluorescence". Physical Review Letters 39 (11): 691–695. Bibcode 1977PhRvL..39..691K. DOI:10.1103/PhysRevLett.39.691.
- Pais, A. (1982). Subtle is the Lord: The Science and the Life of Albert Einstein. Oxford University Press.
- Grangier, P.; Roger, G.; Aspect, A.
(1986). "Experimental Evidence for a Photon Anticorrelation Effect on a
Beam Splitter: A New Light on Single-Photon Interferences". Europhysics Letters 1 (4): 173–179. Bibcode 1986EL......1..173G. DOI:10.1209/0295-5075/1/4/004.
- Lamb, W.E. (1995). "Anti-photon". Applied Physics B 60 (2–3): 77–84. Bibcode 1995ApPhB..60...77L. DOI:10.1007/BF01135846.
- Special supplemental issue of Optics and Photonics News (vol. 14, October 2003) article web link[dead link]
- Roychoudhuri, C.; Rajarshi, R. (2003). "The nature of light: what is a photon?". Optics and Photonics News 14: S1 (Supplement).[dead link]
- Zajonc, A.. "Light reconsidered". Optics and Photonics News 14: S2–S5 (Supplement).
- Loudon, R.. "What is a photon?". Optics and Photonics News 14: S6–S11 (Supplement).
- Finkelstein, D.. "What is a photon?". Optics and Photonics News 14: S12–S17 (Supplement).
- Muthukrishnan, A.; Scully, M.O.; Zubairy, M.S.. "The concept of the photon—revisited". Optics and Photonics News 14: S18–S27 (Supplement).
- Mack, H.; Schleich, W.P.. "A photon viewed from Wigner phase space". Optics and Photonics News 14: S28–S35 (Supplement).
- Glauber, R. (2005). "One Hundred Years of Light Quanta". 2005 Physics Nobel Prize Lecture.
Education with single photons:
- Thorn, J.J.; Neel, M.S.; Donato, V.W.; Bergreen, G.S.; Davies, R.E.; Beck, M. (2004). "Observing the quantum behavior of light in an undergraduate laboratory". American Journal of Physics 72 (9): 1210–1219. Bibcode 2004AmJPh..72.1210T. DOI:10.1119/1.1737397.
- Bronner, P.; et al., Andreas; Silberhorn, Christine; Meyn, Jan-Peter (2009). "Interactive screen experiments with single photons". European Journal of Physics 30 (2): 345–353. Bibcode 2009EJPh...30..345B. DOI:10.1088/0143-0807/30/2/014.